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Thermochemical properties of lanthanides (Ln = La, Nd) and actinides (An = U, Np, Pu, Am) in the molten LiCl–KCl eutectic by Patrick Masset; Rudy J.M. Konings; Rikard Malmbeck; Jérôme Serp; Jean-Paul Glatz is a Materials Science article available to read on EtoBox.

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The electrochemical reduction of actinides (U, Pu, Np and Am) and lanthanides (La and Nd) chlorides was investigated by cyclic voltammetry and chronopotentiometry at different temperatures in LiCl-KCl eutectic. The diffusion coefficients of these metallic cations were estimated as well as their apparent standard potentials. These values of potentials are compared with existing data measured also by transient electrochemical techniques or e.m.f. measurements.

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Author

Patrick Masset; Rudy J.M. Konings; Rikard Malmbeck; Jérôme Serp; Jean-Paul Glatz

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-3115)

Published

2005

Language

EN

Field

Materials Science (Physical Sciences)