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Palladium(II) complexes of 1,4,7-triazacyclononane ([9]aneN3) by T.N. Margulis; Leverett J. Zompa is a Chemistry article available to read on EtoBox.

What is Palladium(II) complexes of 1,4,7-triazacyclononane ([9]aneN3) about?

The syntheses of several Pd(I1) complexes of 1,4,7-triazacyclononane, [9]aneN,, and the molecular structure of two complexes by X-ray diffraction are reported. The diprotonated bis complex, [Pd(HL),](ClO&-H20, contains the ligands in the anti conformation and is structurally similar to the previously reported non-protonated PdL\*+ in [PdL]PFs. The acidity constants (pK,) of Pd(HL),"' in 0.1 M C104-at 25 "C are 2.40 and 4.72, respectively. The structure of the protonated mono complex, [PdHLBr,]CIO,, is also determined.

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Author
T.N. Margulis; Leverett J. Zompa
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
Published
1992
Language
EN
Field
Chemistry (Physical Sciences)

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