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What is Spin Crossover in Heteroleptic Fe(III) Complexes about?

The study investigates the spin crossover (SCO) transition of a neutral heteroleptic Fe(III) complex, revealing that next-nearest neighbor dispersion interactions significantly contribute to the transition enthalpy differences. The complex exhibited an abrupt SCO transition at room temperature, with thermodynamic parameters derived from magnetic susceptibility and crystal structure analyses. The findings emphasize the importance of considering both nearest and next-nearest neighbor interactions in understan

Author

henryk hencio

Language

EN