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Kinetics of the Anionic Coordination Dimerization of Isoprene by Jan Bartoňa, Miroslav Kašparb and Vlastimil Růžičkaa is a Chemistry article available to read on EtoBox.

What is Kinetics of the Anionic Coordination Dimerization of Isoprene about?

The kinetics of the anionic coordination dimerization of isoprene (i.e., 2-methyl-1,3-butadiene) to β-myrcene (i.e., 7-methyl-3-methylene-1,6-octadiene) was investigated. The reaction was initiated with sodium in the presence of dicyclohexyl amine in tetrahydrofuran. Kinetic measurements showed that ionic pairs of isoprenyl sodium were additionally solvated by two molecules of tetrahydrofuran. A kinetic model of the reaction enabled the time dependence of the isoprene concentration to be expressed in terms of a two-parameter equation.

Who reads Kinetics of the Anionic Coordination Dimerization of Isoprene?

Author

Jan Bartoňa, Miroslav Kašparb and Vlastimil Růžičkaa

Publisher

UOCHB; Institute of Organic Chemistry & Biochemistry, Academy of Sciences of the Czech Republic; Akademie Ved Ceske Republiky; Institute of Organic Chemistry & Biochemistry (ISSN 0010-0765)

Published

1982

Language

EN

Field

Chemistry (Physical Sciences)