Opening book details…
Can I read 1,1-Bis(1′′,2′′,3′′,4′′,5′′-pentamethylferrocen-1′-yl)ethene on EtoBox?
1,1-Bis(1′′,2′′,3′′,4′′,5′′-pentamethylferrocen-1′-yl)ethene by Oliver M. Heigl; Martin A. Herker; Wolfgang Hiller; Frank H. Köhler; Andreas Schell is a Chemistry article available to read on EtoBox.
What is 1,1-Bis(1′′,2′′,3′′,4′′,5′′-pentamethylferrocen-1′-yl)ethene about?
1,1-Bis(1¦,2¦,3¦,4¦,5¦-pentamethylferrocen-1%-yl)ethene ( ) was synthezised as a prototype of two metallocenes that are bridged by the sp 2 -carbon center of a vinylidene group. Starting from 6-N,N-dimethylamino-6-methylfulvene, the iron-containing intermediates were a pentamethylferrocenyl-substituted fulvene and an ethene that was geminally disubstituted by a Cp anion and a pentamethylferrocenyl moiety. Besides other methods, the ferrocenes were characterized by NMR spectroscopy including full signal assignment. The bimetallic compound 6 showed moderate interactions between the two ferrocenes in the cyclic voltammogram (DE 1/2 =150 mV). According to X-ray crystal structure analysis compound 6 is a twisted molecule; the vinylidene moiety and the Cps of the neighboring ferrocenes are not coplanar.
Who reads 1,1-Bis(1′′,2′′,3′′,4′′,5′′-pentamethylferrocen-1′-yl)ethene?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Oliver M. Heigl; Martin A. Herker; Wolfgang Hiller; Frank H. Köhler; Andreas Schell
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 1999
- Language
- EN
- Field
- Chemistry (Physical Sciences)