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Investigating the Electrochemically Driven Capture and Release of Long-Chain PFAS by Redox Metallopolymer Sorbents by Paola Baldaguez Medina; Valentina Ardila Contreras; Frank Hartmann; Deborah Schmitt; Angelique Klimek; Johannes Elbert; Markus Gallei; Xiao Su is a Engineering article available to read on EtoBox.

What is Investigating the Electrochemically Driven Capture and Release of Long-Chain PFAS by Redox Metallopolymer Sorbents about?

The remediation of perfluoroalkyl substances (PFAS) is an urgent challenge due to their prevalence and persistence in the environment. Electrosorption is a promising approach for wastewater treatment and water purification, especially through the use of redox polymers to control the binding and release of target contaminants without additional external chemical inputs. However, the design of efficient redox electrosorbents for PFAS faces the significant challenge of balancing a high adsorption capacity while maintaining significant electrochemical regeneration. To overcome this challenge, we investigate redox-active metallopolymers as a versatile synthetic platform to enhance both electrochemical reversibility and electrosorption uptake capacity for PFAS removal. We selected and synthesized a series of metallopolymers bearing ferrocene and cobaltocenium units spanning a range of redox potentials to evaluate their performance for the capture and release of perfluorooctanoic acid (PFOA). Our results demonstrate that PFOA uptake and regeneration efficiency increased with more negative formal potential of the redox polymers, indicating possible structural correlations with the electron

Who reads Investigating the Electrochemically Driven Capture and Release of Long-Chain PFAS by Redox Metallopolymer Sorbents?

It is typically read by researchers, students, and practitioners in Engineering.

Author
Paola Baldaguez Medina; Valentina Ardila Contreras; Frank Hartmann; Deborah Schmitt; Angelique Klimek; Johannes Elbert; Markus Gallei; Xiao Su
Publisher
American Chemical Society (ACS)
Published
2023
Language
EN
Field
Engineering (Physical Sciences)

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