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Binding property and redox behaviour of nickel(II) macrocyclic complex containing crown ether toward alkaline earth metal ions by Joo-Eun Jee; Man Chai Chang; Chee-Hun Kwak is a Materials Science article available to read on EtoBox.

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The binding constants of [Ni(L 1 )] 2þ toward alkaline earth metal ions are relatively small compared with those of free 18-crown-6 and those of [Ni(L 1 )] 2þ toward the alkali metal ions. The reduction potential of the [Ni(L 1 )](ClO 4 ) 2 in the presence of alkaline earth metal ions shifts to the positive direction in the order Mg 2þ < Ca 2þ < Sr 2þ and K red /K ox value of this redox process is increased in the

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Author

Joo-Eun Jee; Man Chai Chang; Chee-Hun Kwak

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1387-7003)

Published

2004

Language

EN

Field

Materials Science (Physical Sciences)