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Investigation of Methylaluminoxane as a Cocatalyst for the Polymerization of 1,3-Butadiene to Highcis-1,4-polybutadiene by Peter Cass; Kerry Pratt; Terry Mann; Bob Laslett; Ezio Rizzardo; Robert Burford is a Materials Science article available to read on EtoBox.
What is Investigation of Methylaluminoxane as a Cocatalyst for the Polymerization of 1,3-Butadiene to Highcis-1,4-polybutadiene about?
The catalytic system Co/methylaluminoxane/tert-butyl chloride has been studied and optimized for the polymerization of 1,3-butadiene to high cis-1,4-polybutadiene. The ratio of the individual catalyst components was investigated to achieve maximum conversion, stereoregularity, and molecular weight. It was found that the specific order of addition of catalyst components to the feedstock and aging time therein has critical influence in the polymerization reaction. This can be attributed to the rate of chlorinating the aluminoxane and the stability of the active catalyst sites obtained.
Who reads Investigation of Methylaluminoxane as a Cocatalyst for the Polymerization of 1,3-Butadiene to Highcis-1,4-polybutadiene?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Peter Cass; Kerry Pratt; Terry Mann; Bob Laslett; Ezio Rizzardo; Robert Burford
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 1999
- Language
- EN
- Field
- Materials Science (Physical Sciences)