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Pressure and solvent effects on the kinetics of a Menshutkin reaction in aliphatic alcohols by César A. N. Viana; António R. T. Calado; Lídia M. V. Pinheiro is a Chemistry article available to read on EtoBox.

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## Abstract The kinetics of the Menshutkin reaction between triethylamine and iodoethane was studied at 313 K in seven primary and secondary alkanols. An accurate conductimetric method was employed to obtain second‐order rate constants at pressures of 0·1–200 MPa. Volumes and isothermal compressions of activation were calculated by different model‐based equations which are compared. Activation volumes at 0·1 MPa are in the range −26 to −33 cm^3^ mol^−1^. Procedures for dissecting intra‐ and intermolecular contributions to the volume of activation are discussed. A clear dependence of model parameters on the solvent volumetric properties was found.

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Author

César A. N. Viana; António R. T. Calado; Lídia M. V. Pinheiro

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0894-3230)

Published

1995

Language

EN

Field

Chemistry (Physical Sciences)