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CHEMPR1609_proof_v8i9.pdf -1 Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in situ surface-enhanced Rama ... 2 Introduction 2 Results and discussions 3 In-situ SERS studies of benzene, naphthalene, and phenanthrene adsorbed on colloidal Au 3 Developing an atomistic picture of π-metal interactions on ligand-protected Au nanosurfaces 5 Rationalizing PAH adsorption on Au nanomaterials under ambient conditions 7 π-metal interactions on colloidal Ag nanoparticles 8 Applications of π-metal interactions in sensing 10 Experimental procedures 11 Resource availability 11 Lead contact 11 Materials availability 11 Data and code availability 11 Synthesis of plasmonic nanoparticles 11 Formation of MeLLFs 11 SERS 12 SERS using MeLLFs 12 SERS using aggregated colloids 12 Raman spectroscopy 13 Other characterizations 13 Computational method 13 Supplemental information 13 Acknowledgments 13 Author contributions 14 Declaration of interests 14 References 14
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