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On the Translationally Activated Dissociative Chemisorption of Hydrogen and Deuterium at a Nickel (111) Surface by D.O. Hayward; A.O. Taylor is a Physics and Astronomy article available to read on EtoBox.

What is On the Translationally Activated Dissociative Chemisorption of Hydrogen and Deuterium at a Nickel (111) Surface about?

A statistical model has been developed which accurately describes the dependence of the sticking probability at normal incidence (S.) on translational energy (Et) for HZ and D, on a Ni( 111) surface according to the equation S,=CE;' (E, -&)\*, where E0 (the threshold energy) and Care constants which are equal to 0.85 kJ mol-' and 0.02 mol l& ', respectively. This result is consistent with a "freely" rotating transition state complex. For a surface temperature 'f, of 1143 K the model yields an angularly independent mean energy of desorption of 3.09kT,, which is in reasonable agreement with the experimental result of 2.9kT,.

Who reads On the Translationally Activated Dissociative Chemisorption of Hydrogen and Deuterium at a Nickel (111) Surface?

It is typically read by researchers, students, and practitioners in Physics and Astronomy.

Author
D.O. Hayward; A.O. Taylor
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)
Published
1988
Language
EN
Field
Physics and Astronomy (Physical Sciences)

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