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Self-healing anticorrosive coatings inspired by the biomimetic porous organic cage nanocontainer for mussels 1 1 Introduction 1 2 Experimental section 2 2.1 Materials 2 2.2 Preparation of Ti3C2Tx nanosheets 2 2.3 Preparation of HE-Ti3C2Tx 2 2.4 Preparation of HE-Ti3C2Tx-Ce 2 2.5 Preparation of corrosion inhibition solutions and epoxy composite coatings 2 2.6 Measurements and characterization 2 3 Results and discussion 3 3.1 Characterization of the HNQ-EN 3 3.2 SEM and TEM analysis 3 3.3 FT-IR and Raman analysis 4 3.4 XRD analysis 4 3.5 XPS analysis 4 3.6 Thermal analysis 5 3.7 Electrochemical analysis of steel electrodes in the solutions 5 3.8 Potentiodynamic polarization 8 3.9 Corrosion products characterization 8 3.10 Electrochemical impedance measurement 8 3.11 Corrosion morphology 9 4 Conclusions 12 Credit author statement 12 Declaration of competing interest 12 Data availability 12 Acknowledgements 12 Appendix A Supplementary data 12 References 12
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