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Structure of Zr2(WO4)(PO4)2 from Powder X-Ray Data: Cation Ordering with No Superstructure by J.S.O. Evans; T.A. Mary; A.W. Sleight is a Materials Science article available to read on EtoBox.
What is Structure of Zr2(WO4)(PO4)2 from Powder X-Ray Data: Cation Ordering with No Superstructure about?
The ab initio structure determination of \(\mathrm{Zr}_{2}\left(\mathrm{WO}_{4}\right)\left(\mathrm{PO}_{4}\right)_{2}\) from room temperature powder X-ray diffraction data is reported. This compound crystallizes in the orthorhombic space group Pnca with \(a=9.35451(9), b=12.31831(9)\), and \(c=9.16711(8) \AA\) Â. The structure is based on \(\mathrm{ZrO}_{6}\) octahedra sharing corners with \(\mathrm{WO}_{4}\) and \(\mathrm{PO}_{4}\) tetrahedra. Although \(\mathrm{Zr}_{2}\left(\mathrm{WO}_{4}\right)\left(\mathrm{PO}_{4}\right)_{2}\) is isostructural with \(\mathrm{Fe}_{2}\left(\mathrm{MoO}_{4}\right)_{3}\) and its \(\mathrm{WO}_{4}\) and \(\mathrm{PO}_{4}\) tetrahedra are well ordered, no superstructure or change in space group is required to account for this ordering. \(\odot 1995\) Academic Press, nc.
Who reads Structure of Zr2(WO4)(PO4)2 from Powder X-Ray Data: Cation Ordering with No Superstructure?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- J.S.O. Evans; T.A. Mary; A.W. Sleight
- Publisher
- Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 0022-4596)
- Published
- 1995
- Language
- EN
- Field
- Materials Science (Physical Sciences)