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Electrochemical synthesis of benzothiazole-2-thionato complexes of nickel(II), Zinc(II) and cadmium(II): the crystal structure of 2,2′-bipyridine bis(benzothiazole-2-thionato)zinc(II) by Rosa Castro; Jose A. Garcia-Vazquez; Jaime Romero; Antonio Sousa; Charles A. McAuliffe; Robin Pritchard is a Chemistry article available to read on EtoBox.

What is Electrochemical synthesis of benzothiazole-2-thionato complexes of nickel(II), Zinc(II) and cadmium(II): the crystal structure of 2,2′-bipyridine bis(benzothiazole-2-thionato)zinc(II) about?

The electrochemical oxidation of anodic metal (nickel, zinc or cadmium) in acetonitrile solutions of henzothiazole-2-thione (Hbztz) gave the compounds [M(bztz)z] [M = nickel(II), zinc(I1) and cadmium(II)]. When the oxidations were repeated in the presence of neutral ligands L' (2,2'-bipyridine or l,lO-phenanthroline) the complexes [M(bztz),L] were obtained. The crystal structure of 2,2'-bipyridine bis(benzothiazole-2thionato)zinc(II) was determined by X-ray diffraction. This compound consists of monomeric molecules in which the central ZnS2N2 unit has a slightly distorted tetrahedral environment. The electronic, IR and 'H and 13C NMR spectra of the complexes are discussed and related to their structure.

Who reads Electrochemical synthesis of benzothiazole-2-thionato complexes of nickel(II), Zinc(II) and cadmium(II): the crystal structure of 2,2′-bipyridine bis(benzothiazole-2-thionato)zinc(II)?

Author

Rosa Castro; Jose A. Garcia-Vazquez; Jaime Romero; Antonio Sousa; Charles A. McAuliffe; Robin Pritchard

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)

Published

1993

Language

EN

Field

Chemistry (Physical Sciences)