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Voltammetric Behavior and Determination of Tocopherols with Partial Least Squares Calibration: Analysis in Vegetable Oil Samples by T Galeano Diaz; I Durán Merás; A Guiberteau Cabanillas; M.F Alexandre Franco is a Chemistry article available to read on EtoBox.

What is Voltammetric Behavior and Determination of Tocopherols with Partial Least Squares Calibration: Analysis in Vegetable Oil Samples about?

The voltammetric behavior of Vitamin E in the presence of olive oil is studied at the glassy carbon electrode, in a hexane-ethanol medium, with diverse techniques: sampled DC, differential pulse, and square-wave voltammetry. The influence of such variables as the hexane-ethanol proportion, sulfuric acid concentration, and instrumental parameters is studied. Separate voltammetric peaks are obtained for ␣-tocopherol and ␦-tocopherol, but the peaks for ␤-tocopherol and ␥-tocopherol overlap. For the simultaneous determination of ␣-, ␤ + ␥-, and ␦-tocopherols in vegetable oils by the PLS-1 multivariate calibration method, the results using sampled DC and DPV voltammograms are compared. The DPV voltammograms are found to be the best data set. The proposed method is applied to the determination of the tocopherols in different vegetable oil samples. The olive oil samples needed a prior cleaning stage by solid-phase extraction on silica cartridges. The results are very acceptable.

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Author

T Galeano Diaz; I Durán Merás; A Guiberteau Cabanillas; M.F Alexandre Franco

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0003-2670)

Published

2004

Language

EN

Field

Chemistry (Physical Sciences)