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Direct Heteroarylation Guidelines for Well-Defined Thiophene-Based Conjugated Molecules by Mona Hamidzad Sangachin; Samuel Brassard; Mario Leclerc is a Chemistry article available to read on EtoBox.

What is Direct Heteroarylation Guidelines for Well-Defined Thiophene-Based Conjugated Molecules about?

Direct (hetero)arylation polymerization (DHAP) shows great promise for simple, low cost, and benign preparation of conjugated polymers. However, coupling selectivity has always posed a problem. Herein, direct (hetero)arylation was studied on small molecule models to develop suitable conditions for C-C couplings between 2-methylthiophene acting as an electron-donating moiety and 2-thiophenecarbonitrile acting as an electron-withdrawing moiety, when one of the partners is brominated. We observed that the best conditions are obtained when the electronwithdrawing moiety is halogenated.

Who reads Direct Heteroarylation Guidelines for Well-Defined Thiophene-Based Conjugated Molecules?

Author

Mona Hamidzad Sangachin; Samuel Brassard; Mario Leclerc

Publisher

American Chemical Society (ACS)

Published

2023

Language

EN

Field

Chemistry (Physical Sciences)