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The study investigates the correlation between the crystal structure and morphology of silver dendritic nanostructures produced via potentiostatic electrodeposition from different electrolytes. It was found that needle-like and fern-like dendrites formed from nitrate electrolyte at varying overpotentials, while pine-like dendrites emerged from ammonium electrolyte, with significant changes in crystal orientation and specific surface area observed. The average crystallite sizes of the silver particles were d

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