Can I read Polyhedral Molybdenaborane Chemistry:nido-6-molybdenadecaboranes including the molecular structure of [6,6,6,6-(CO)2(PMe2Ph)2-nido-6-MoB9H12-5-Cl] Some Structural Intercomparisons on EtoBox?

Polyhedral Molybdenaborane Chemistry:nido-6-molybdenadecaboranes including the molecular structure of [6,6,6,6-(CO)2(PMe2Ph)2-nido-6-MoB9H12-5-Cl] Some Structural Intercomparisons by Prof. Dr. Dr. h. c. N. N. Greenwood; Dr. J. D. Kennedy; I. Macpherson; Dr. M. Thornton-Pett is a Chemistry article available to read on EtoBox.

What is Polyhedral Molybdenaborane Chemistry:nido-6-molybdenadecaboranes including the molecular structure of [6,6,6,6-(CO)2(PMe2Ph)2-nido-6-MoB9H12-5-Cl] Some Structural Intercomparisons about?

3 have been prepared and characterized by multielement n.m.r. spectroscopy (lH, llB, and 3lP). The fluxional properties of the oxopolyhedral ligands on the metal centres have also been studied, leading to activation energies AG (at the coalescence temperature) of 44 f 2 kJ mol-l (at -34°C) for 1 and 52 f 2 k J mol-l (at 6.5"C) for 3. The detailed structure of 3 has been established by single-crystal X-ray diffraction analysis using 3350 "observed" reflections and 337 parameters (R = 0.0268, R' = 0.0299). The monoclinic crystals have a = 1590.3(2), b = 1028.4(2), and c = 1696.4(1) pm, B = 94.30(1)', space group P2,/c and Z = 4. The results allow comparison with other previously synthesized nido-6-metalladecaborane clusters in which the heteroatom is tungsten, rhenium, osmium, or ruthenium.

Who reads Polyhedral Molybdenaborane Chemistry:nido-6-molybdenadecaboranes including the molecular structure of [6,6,6,6-(CO)2(PMe2Ph)2-nido-6-MoB9H12-5-Cl] Some Structural Intercomparisons?

Author

Prof. Dr. Dr. h. c. N. N. Greenwood; Dr. J. D. Kennedy; I. Macpherson; Dr. M. Thornton-Pett

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

1986

Language

EN

Field

Chemistry (Physical Sciences)