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Can I read Ring-methyl activation in pentamethylcyclopentadienyl complexes 7 reactions of [Ru(η2:η5-C5Me4CH2O(CH2)nCH=CHR2)(CO)2]+BF4− with nucleophiles on EtoBox?
Ring-methyl activation in pentamethylcyclopentadienyl complexes 7 reactions of [Ru(η2:η5-C5Me4CH2O(CH2)nCH=CHR2)(CO)2]+BF4− with nucleophiles by Oleg V. Gusev; Larisa N. Morozova; Tat'ayana A. Peganova; Mikhail Yu. Antipin; Konstantin A. Lyssenko; Alfred F. Noels; Shane R. O'Leary; Peter M. Maitlis is a Chemistry article available to read on EtoBox.
What is Ring-methyl activation in pentamethylcyclopentadienyl complexes 7 reactions of [Ru(η2:η5-C5Me4CH2O(CH2)nCH=CHR2)(CO)2]+BF4− with nucleophiles about?
The ruthenium chelates containing tethered olefinic side chains [Ru(r/2:@-C5Me4CH20(CH2)nCH=CHR2XCO)e]+BF4 (la, R 2 = H, n = 1; lb, R 2 = Me, n = 1; lc, R 2 = H, n = 2) react with NaBH 4 in MeOH or in water to give the non-chelated olefin hydride complexes [Ru(@-CsMe4CH20(CH2)nCH=CHR2)(CO)2(H)] (2a-c). By contrast, alkoxide attacked at a carbonyl ligand in la giving the chelated olefin alkoxycarbonyl complexes [Ru(r/2:@-CsMe4CH 2OCH2CH=CH2)(r/I-COOR3)(CO)] (3a,a', R 3 = Me; 4a,a', R 3 = Et), which form a separable mixture of diastereomers. There was no evidence for attack at the coordinated olefin in complex 1.
Who reads Ring-methyl activation in pentamethylcyclopentadienyl complexes 7 reactions of [Ru(η2:η5-C5Me4CH2O(CH2)nCH=CHR2)(CO)2]+BF4− with nucleophiles?
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- Author
- Oleg V. Gusev; Larisa N. Morozova; Tat'ayana A. Peganova; Mikhail Yu. Antipin; Konstantin A. Lyssenko; Alfred F. Noels; Shane R. O'Leary; Peter M. Maitlis
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 1997
- Language
- EN
- Field
- Chemistry (Physical Sciences)