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Synthesis of Bio-based Methylcyclopentadiene via Direct Hydrodeoxygenation of 3-Methylcyclopent-2-enone Derived from Cellulose by Liu, Yanting ;Wang, Ran ;Qi, Haifeng ;Liu, Xiao Yan ;Li, Guangyi ;Wang, Aiqin ;Wang, Xiaodong ;Cong, Yu ;Zhang, Tao ;Li, Ning is a Biochemistry, Genetics and Molecular Biology article available to read on EtoBox.
What is Synthesis of Bio-based Methylcyclopentadiene via Direct Hydrodeoxygenation of 3-Methylcyclopent-2-enone Derived from Cellulose about?
## Abstract The exploration of highly efficient processes to convert renewable biomass to fuels and value-added chemicals is stimulated by the energy and environment problems. Herein, we describe an innovative route for the production of methylcyclopentadiene (MCPD) with cellulose, involving the transformation of cellulose into 3-methylcyclopent-2-enone (MCP) and subsequent selective hydrodeoxygenation to MCPD over a zinc-molybdenum oxide catalyst. The excellent performance of the zinc-molybdenum oxide catalyst is attributed to the formation of ZnMoO~3~ species during the reduction of ZnMoO~4~. Experiments reveal that preferential interaction of ZnMoO~3~ sites with the C=O bond instead of C=C bond in vapor-phase hydrodeoxygenation of MCP leads to highly selective formations of MCPD (with a carbon yield of 70%).
Who reads Synthesis of Bio-based Methylcyclopentadiene via Direct Hydrodeoxygenation of 3-Methylcyclopent-2-enone Derived from Cellulose?
It is typically read by researchers, students, and practitioners in Biochemistry, Genetics and Molecular Biology.
- Author
- Liu, Yanting ;Wang, Ran ;Qi, Haifeng ;Liu, Xiao Yan ;Li, Guangyi ;Wang, Aiqin ;Wang, Xiaodong ;Cong, Yu ;Zhang, Tao ;Li, Ning
- Publisher
- Springer Science and Business Media LLC
- Published
- 2021
- Language
- EN
- Field
- Biochemistry, Genetics and Molecular Biology (Life Sciences)