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Can I read ChemInform Abstract: Tin-Containing Nasicon-Related Compounds: A New Mixed Valence Compound, Sn0.5Sn2P3O12, Containing Sn4+ and Sn2+ and Lithium Incorporation within CuSn2P3O12. on EtoBox?
ChemInform Abstract: Tin-Containing Nasicon-Related Compounds: A New Mixed Valence Compound, Sn0.5Sn2P3O12, Containing Sn4+ and Sn2+ and Lithium Incorporation within CuSn2P3O12. by F. J. BERRY; R. C. THIED is a Chemistry article available to read on EtoBox.
What is ChemInform Abstract: Tin-Containing Nasicon-Related Compounds: A New Mixed Valence Compound, Sn0.5Sn2P3O12, Containing Sn4+ and Sn2+ and Lithium Incorporation within CuSn2P3O12. about?
Tin-Containing Nasicon-Related Compounds: A New Mixed Valence Compound, Sn0.5Sn2P3O12, Containing Sn4+ and Sn2+ and Lithium Incorporation within CuSn2P3O12. -The novel mixed valence tin compound Sn0.5Sn2P3O12 is prepared by sequential heating of a stoichiometric mixture of SnO and SnO2 to 1000 • C. As revealed from the powder XRD pattern and the 119Sn Moessbauer or chemical isomer shift data recorded for Sn2+ at 298 K and 77 K, the nasicon-related compound contains highly ionic Sn2+ within the Type I sites in the channels. Treatment of the light green compound CuSn2P3O12 with BuLi yields a black solid due to reduction of Cu+ ions in off-centered positions in the Type I sites by incorporation of Li+ and segregation of Cu0 to the exterior of the structure as shown from the
Who reads ChemInform Abstract: Tin-Containing Nasicon-Related Compounds: A New Mixed Valence Compound, Sn0.5Sn2P3O12, Containing Sn4+ and Sn2+ and Lithium Incorporation within CuSn2P3O12.?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- F. J. BERRY; R. C. THIED
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley (ISSN 0931-7597)
- Published
- 1997
- Language
- EN
- Field
- Chemistry (Physical Sciences)