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Photolysis of organopolysilanes. Reactions of trimethylsilylphenylsilylene with allylic halides and allyl ethyl ether by Mitsuo Ishikawa; Ken-Ichi Nakagawa; Makoto Kumada is a Chemistry article available to read on EtoBox.

What is Photolysis of organopolysilanes. Reactions of trimethylsilylphenylsilylene with allylic halides and allyl ethyl ether about?

The photolysis of tris(trimethylsilyl)phenylsilane (I) in the presence of allyl chloride, allyl bromide, 2-cyclohexenyl chloride, 2-cyclohexenyl bromide and 2-methylallyl chloride resulted in formation of the respective 1-(2-alkenyl)-1-halo-l-phenyltrimethyldisilanes in moderate yields. Irradiation of I in the presence of crotyl chloride, 1-methylallyl chloride, prenyl chloride and 1,1dimethylallyl chloride afforded the corresponding ~-and 7-substituted chlorodisilanes. Photolysis of I in the presence of allyl ethyl ether produced 1-phenyl-1-trimethylsilyl-2-ethoxymethyl-l-silacyclopropane, although this product was not isolated. The reaction of this silacyclopropane with hydrogen chloride, methanol and boron trifluoride etherate is described.

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Author

Mitsuo Ishikawa; Ken-Ichi Nakagawa; Makoto Kumada

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1981

Language

EN

Field

Chemistry (Physical Sciences)