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Can I read A Family of Cagelike Mn-Silsesquioxane/Bathophenanthroline Complexes: Synthesis, Structure, and Catalytic and Antifungal Activity on EtoBox?

A Family of Cagelike Mn-Silsesquioxane/Bathophenanthroline Complexes: Synthesis, Structure, and Catalytic and Antifungal Activity by Alexey N. Bilyachenko; Evgenii I. Gutsul; Victor N. Khrustalev; Olga Chusova; Pavel V. Dorovatovskii; Vusala A. Aliyeva; Ana B. Paninho; Ana V. M. Nunes; Kamran T. Mahmudov; Elena S. Shubina; Armando J. L. Pombeiro is a Chemistry article available to read on EtoBox.

What is A Family of Cagelike Mn-Silsesquioxane/Bathophenanthroline Complexes: Synthesis, Structure, and Catalytic and Antifungal Activity about?

This study reports a novel family of cage manganesesilsesquioxanes prepared via complexation with bathophenanthroline (4,7-diphenyl-1,10phenanthroline). The resulting Mn 4 -, Mn 6 Li 2 -, and Mn 4 Na-compounds exhibit several unprecedented cage metallasilsesquioxane structural features, including intriguing self-assembly of silsesquioxane ligands. Complexes were tested in vitro for fungicidal activity against seven classes of phytopathogenic fungi. The representative Mn 4 Na-complex acts as a catalyst in the cycloaddition of CO 2 to epoxides under solvent-free conditions to form cyclic carbonates in good yields.

Who reads A Family of Cagelike Mn-Silsesquioxane/Bathophenanthroline Complexes: Synthesis, Structure, and Catalytic and Antifungal Activity?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Alexey N. Bilyachenko; Evgenii I. Gutsul; Victor N. Khrustalev; Olga Chusova; Pavel V. Dorovatovskii; Vusala A. Aliyeva; Ana B. Paninho; Ana V. M. Nunes; Kamran T. Mahmudov; Elena S. Shubina; Armando J. L. Pombeiro
Publisher
American Chemical Society (ACS)
Published
2023
Language
EN
Field
Chemistry (Physical Sciences)

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