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What is Term Symbols for Diatomic Molecules about?

1. For diatomic molecules with non-zero orbital angular momentum (Λ ≠ 0) and non-zero spin (S ≠ 0), the spin-orbit interaction between Λ and the spin angular momentum (Σ) must be considered. 2. This interaction leads to a splitting of electronic energy levels described by the Hamiltonian Te = T0 + AΛΣ, where A is the spin-orbit coupling constant. 3. The sign and magnitude of A determines whether the splitting is "regular" or "inverted" and the size of the energy separations between levels.

Author

Pramod AG

Language

EN