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Simultaneous soot combustion and nitrogen oxides storage on potassium-promoted hydrotalcite-based CoMgAlO catalysts by Qian Li; Ming Meng; Zhi-Qiang Zou; Xin-Gang Li; Yu-Qing Zha is a Environmental Science article available to read on EtoBox.

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A series of potassium-promoted hydrotalcite-based CoMgAlO mixed oxide catalysts used for simultaneous soot combustion and nitrogen oxides storage were prepared by impregnation method. The techniques of TG/DTA, XRD, H 2 -TPR and in situ DRIFTS were employed for catalyst characterization. Over the catalyst containing 7.5% or 10% K, the soot ignition temperature (T i = 260 • C) and total removal temperature (T f = 390 • C) are decreased by 180 • C and 273 • C, respectively, as compared with the uncatalyzed reaction. The results of kinetic calculation show that the presence of K-promoted catalysts decreases the activation energy of soot combustion from 207 kJ/mol to about 160 kJ/mol. When 400 ppm NO is introduced, lower characteristic temperatures or higher reaction rate for soot oxidation is achieved. Simultaneously, relatively larger nitrogen oxides storage capacity is obtained. It is revealed by H 2 -TPR that the addition of K increases the amount of active Co sites and the mobility of bulk lattice oxygen due to the low melting point of K-containing compounds, the low valence of K + and the strong interaction between K and Mg(Al). For nitrogen oxides storage, different routes via ch

Who reads Simultaneous soot combustion and nitrogen oxides storage on potassium-promoted hydrotalcite-based CoMgAlO catalysts?

Author

Qian Li; Ming Meng; Zhi-Qiang Zou; Xin-Gang Li; Yu-Qing Zha

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0304-3894)

Published

2009

Language

EN

Field

Environmental Science (Physical Sciences)