Can I read Photolytic CO-substitution reaction of organoiron thiocarboxylate derivatives CpFe(CO)2SCOR (R=alkyl, aryl) with diphosphines (Ph2P(CH2)nPPh2) (n=1–6): X-ray crystal structure of [CpFe(dppm)SCO(3,5-(NO2)2C6H3)] on EtoBox?

Photolytic CO-substitution reaction of organoiron thiocarboxylate derivatives CpFe(CO)2SCOR (R=alkyl, aryl) with diphosphines (Ph2P(CH2)nPPh2) (n=1–6): X-ray crystal structure of [CpFe(dppm)SCO(3,5-(NO2)2C6H3)] by Ibrahim Jibril; Mohammad El-khateeb; Hisham Barakat; Gerd Rheinwald; Heinrich Lang is a Chemistry article available to read on EtoBox.

What is Photolytic CO-substitution reaction of organoiron thiocarboxylate derivatives CpFe(CO)2SCOR (R=alkyl, aryl) with diphosphines (Ph2P(CH2)nPPh2) (n=1–6): X-ray crystal structure of [CpFe(dppm)SCO(3,5-(NO2)2C6H3)] about?

The photolytic CO-substitution reaction of the organoiron thiocarboxylate complexes CpFe(CO) 2 SCOR (R= CH 3 , 2- ] at room temperature using 1:2 (metal-ligand) molar ratio afforded exclusively the disubstituted complexes CpFe(Ph 2 P(CH 2 ) n PPh 2 )SCOR when n= 1, 2 and 3 and the monosubstituted analogs CpFe(CO)(Ph 2 P(CH 2 ) n PPh 2 )SCOR when n =4, 5 and 6. This reaction was found to be strongly influenced by the backbone length of the diphosphine ligand, the nature of the R group of the thiocarboxylate moiety and the metal-ligand molar ratios. The crystal structure of CpFe(dppm)SCO(3,5-(NO 2 ) 2 C 6 H 3 ) was determined.

Who reads Photolytic CO-substitution reaction of organoiron thiocarboxylate derivatives CpFe(CO)2SCOR (R=alkyl, aryl) with diphosphines (Ph2P(CH2)nPPh2) (n=1–6): X-ray crystal structure of [CpFe(dppm)SCO(3,5-(NO2)2C6H3)]?

Author

Ibrahim Jibril; Mohammad El-khateeb; Hisham Barakat; Gerd Rheinwald; Heinrich Lang

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)