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Can I read Ireland–Claisen rearrangement of steroidal Δ23-22-alcohols: an application to Δ22,25-24-alkyl steroid synthesis on EtoBox?
Ireland–Claisen rearrangement of steroidal Δ23-22-alcohols: an application to Δ22,25-24-alkyl steroid synthesis by Vladimir A. Khripach; Vladimir N. Zhabinskii; Olga V. Konstantinova; Natalya B. Khripach is a Chemistry article available to read on EtoBox.
What is Ireland–Claisen rearrangement of steroidal Δ23-22-alcohols: an application to Δ22,25-24-alkyl steroid synthesis about?
A new method for the preparation of a 1,4-diene system in the steroid side chain, providing the possibility of stereocontrol at C-3 has been described. Its usefulness has been examined for Á 22,25 -24-alkyl steroid synthesis. The proposed approach is based on the Ireland±Claisen rearrangement of Á 23 -22-alcohols followed by C-25 silylation of the formed ester and Peterson ole®nation as the ®nal step.
Who reads Ireland–Claisen rearrangement of steroidal Δ23-22-alcohols: an application to Δ22,25-24-alkyl steroid synthesis?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Vladimir A. Khripach; Vladimir N. Zhabinskii; Olga V. Konstantinova; Natalya B. Khripach
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2000
- Language
- EN
- Field
- Chemistry (Physical Sciences)