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A Spectral and Structural Study of the New Cadmium Salt [(H~2~L)~2~][Cd~2~I~6~][(NO~3~)~2~] by Mohammad Hakimi; Zahra Mardani; Keyvan Moeini; Esther Schuh; Fabian Mohr is a Chemistry article available to read on EtoBox.

What is A Spectral and Structural Study of the New Cadmium Salt [(H~2~L)~2~][Cd~2~I~6~][(NO~3~)~2~] about?

The reaction between 2-(piperazin-1-yl)ethanol and cyclohexene oxide under microwave irradiation gave 2-(4-(2-hydroxyethyl)piperazin-1-yl)cyclohexanol (L). The new cadmium salt [(H~2~L)~2~][Cd~2~I~6~][(NO~3~)~2~] (1) was prepared from the reaction of cadmium iodide with L and identified by elemental analysis, FT-IR and Raman spectroscopy, and single-crystal X-ray diffraction. In the crystal structure of 1, there is a [Cd~2~I~6~]^2-^ dianion with distorted tetrahedral geometry for each cadmium atom. The piperazine and cyclohexane rings in 1 have a chair conformation. In the crystal there are several intermolecular hydrogen bonds including N-H···O, O-H···O, O-H···I, C-H···O, and C-H···I interactions.

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Author

Mohammad Hakimi; Zahra Mardani; Keyvan Moeini; Esther Schuh; Fabian Mohr

Publisher

Walter de Gruyter GmbH

Published

2013

Language

EN

Field

Chemistry (Physical Sciences)