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Derivatives of 6-deuterio-D-glucose, absolute configuration at C-6, and steric disposition of an acetoxymethyl group by Didier Gagnaire; Derek Horton; François R. Taravel is a Biochemistry, Genetics and Molecular Biology article available to read on EtoBox.

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## Borodeutende reductron of methyl D-gluco-hexodialdo-l,S-pyranosrde (2) gave a 3 2 mixture of the 6(S) and 6(R) methyl 6-deuteno-a-D-glucopyranosides (3), converted into other products havmg the same eprmenc drstnbution at C-6, mcludmg the tetraacetate (5) of 3, 6-deuteno-D-glucrtol hexaacetate (6), 3,5,6-tn-O-acetyl-6deuteno-1,2-0-rsopropyhdene-c+D-glucofuranose Q, and methyl 2,3-dr-O-acetyl-4,6-0-benzyhdene-6-deuterro-a-n-glucopyranosrde (4) The deutermm-decoupled p m r spectrum of 4 permuted drfferentratron of the 6-eplmers and assrgnment of configuratron at C-6 for the complete series of derivatives The favored, but not exclusive, drsposrtion of the S-acetoxymethyl group m compounds 5-7 has the acetoxyl group antiparallel to C-4

Who reads Derivatives of 6-deuterio-D-glucose, absolute configuration at C-6, and steric disposition of an acetoxymethyl group?

Author

Didier Gagnaire; Derek Horton; François R. Taravel

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0008-6215)

Published

1973

Language

EN

Field

Biochemistry, Genetics and Molecular Biology (Life Sciences)