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Tetraaqua(2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylato-κ2N3,O)cobalt(II) 2.5-hydrate by Sridhar, Balasubramanian ;Ravikumar, Krishnan is a Chemistry article available to read on EtoBox.

What is Tetraaqua(2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylato-κ2N3,O)cobalt(II) 2.5-hydrate about?

The Co II ion in the title compound, [Co(C 5 H 2 N 2 O 4 )(H 2 O) 4 ]Á-2.5H 2 O, is chelated by the orotate dianion through carboxylate O and pyrimidine N atoms, and its octahedral geometry is completed by four water molecules. An intermolecular N-HÁ Á ÁO hydrogen bond forms an orotate-orotate dimer. An extensive three-dimensional hydrogen-bonded network of O-HÁ Á ÁO and N-HÁ Á ÁO bonds and weakinteraction [3.754 (2) A ̊] stabilize the crystal structure. One of the solvent water molecules is located on a twofold rotation axis.

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Author

Sridhar, Balasubramanian ;Ravikumar, Krishnan

Publisher

International Union of Crystallography; Chester UK: International Union of Crystallography, 2001-2014.; [S.l.]: Wiley-Blackwell; [Chester]: 2008-; International Union of Crystallography (IUCr) (ISSN 1600-5368)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)