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## Abstract 1‐Hydroxy‐ and 1‐halocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone. Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the α‐position can be transformed into 1‐substituted cyclopropyl sulfides with a variety of nucleophiles. This means that the usual difficulties encountered with nucleophilic substitution at three‐membered rings ‐ __i.e.__ low rates and ring opening — are largely removed by the presence of an alkylthio group at the same ring carbon atom as the leaving group.

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Author

R. Jorritsma; H. Steinberg; Th. J. de Boer

Publisher

Elsevier Science; Wiley (John Wiley & Sons); Royal Netherlands Chemical Society; Wiley (ISSN 0165-0513)

Published

2010

Language

EN

Field

Chemistry (Physical Sciences)