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Can I read Active site imprinting on Ti oxocluster metal–organic frameworks for photocatalytic hydrogen release from formic acid on EtoBox?
Active site imprinting on Ti oxocluster metal–organic frameworks for photocatalytic hydrogen release from formic acid by Alberto García-Baldoví; Raquel Del Angel; Georges Mouchaham; Shanping Liu; Dong Fan; Guillaume Maurin; Sergio Navalón; Christian Serre; Hermenegildo Garcia is a Engineering article available to read on EtoBox.
What is Active site imprinting on Ti oxocluster metal–organic frameworks for photocatalytic hydrogen release from formic acid about?
On-board hydrogen release from liquid organic carriers is a process that can make feasible the use of H 2 as a transportation fuel. Formic acid is considered as one of the most convenient liquid hydrogen organic carriers, and since it can be easily obtained from CO 2 , it is water soluble which makes it unnecessary to recover the H 2 -depleted byproducts. Compared to the more conventional thermal catalytic decomposition of formic acid, the use of light in combination with a photocatalyst has been much less explored. Herein, we report a new paradigm in MOF photocatalysis with the use of a microporous titanium oxocluster based metal-organic framework (Ti-MOF) endowed with formateimprinted active sites, namely MIP-177-LT (MIP stands for Materials from Institute of Porous Materials of Paris, LT for Low Temperature), as a highly efficient photocatalyst for H 2 release from formic acid without the need to neutralize acidity or use sacrificial agents or noble metals. Noteworthily, a quantum efficiency of 22% has been determined for the photocatalytic H 2 release that is highly remarkable for a non-toxic noble metal-free photocatalyst. Broader context Due to the high mass energy density, g
Who reads Active site imprinting on Ti oxocluster metal–organic frameworks for photocatalytic hydrogen release from formic acid?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Alberto García-Baldoví; Raquel Del Angel; Georges Mouchaham; Shanping Liu; Dong Fan; Guillaume Maurin; Sergio Navalón; Christian Serre; Hermenegildo Garcia
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2023
- Language
- EN
- Field
- Engineering (Physical Sciences)