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Can I read NMR studies of mixed amines on EtoBox?
NMR studies of mixed amines by Mat Ballard; Mark Bown; Susan James; Qi Yang is a Engineering article available to read on EtoBox.
What is NMR studies of mixed amines about?
1 H and quantitative 13 C NMR spectroscopy was used to study the reaction of CO 2 with mixed aqueous amines. This technique permits the measurement of carbamates of each amine and bicarbonate concentrations as a function of time (and loading). The ratio of the amount of each carbamate formed (for primary and secondary amines) is shown to be thermodynamically rather than kinetically controlled, due a rapid exchange reaction between amine and carbamate. This exchange reaction is the likely basis of the "shuttle" mechanism of rate enhancement in mixed amines.
Who reads NMR studies of mixed amines?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Mat Ballard; Mark Bown; Susan James; Qi Yang
- Publisher
- Elsevier ; Elsevier BV (ISSN 1876-6102)
- Published
- 2011
- Language
- EN
- Field
- Engineering (Physical Sciences)
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