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This study investigates the reaction kinetics of atomic chlorine with chlorobenzene using pulsed laser photolysis-time-resolved resonance fluorescence techniques at temperatures ranging from 710 to 1030 K. The rate constant for the reaction is determined to be k1 = (1.36 ± 0.47) × 10^-10 cm3 molecule^-1 s^-1, with the major product pathway leading to the formation of HCl and chlorophenyl radicals. Density functional calculations indicate that the most favorable product is 3-chlorophenyl, resulting from atta

Author

Melina

Language

EN