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Synthesis of trichlorooxo-bis(2,6-dimethylphenylisocyanide) rhenium(V) and crystal structure of μ-oxo-bis[dichlorooxo-bis(2,6-dimethylphenylisocyanide) dirhenium(V)] by F. Ekkehardt Hahn; Lutz Imhof; Thomas Lügger is a Chemistry article available to read on EtoBox.

What is Synthesis of trichlorooxo-bis(2,6-dimethylphenylisocyanide) rhenium(V) and crystal structure of μ-oxo-bis[dichlorooxo-bis(2,6-dimethylphenylisocyanide) dirhenium(V)] about?

The rhenium diisocyanide complex fac-[ Re (O) Ch ( CNC~,H ;-( CH~ ) :-2,6) 2 ] ( 1 ) was obtained by reaction of mer-[ Re( O ) CI 3 ( SMe: ) -(OPPh3) ] with 2 equiv, of the ligand 2,6-dimethylphenylisocyanide. In the presence of water complex I reacts under HC! evolution to yield [ ( 2,6-(CH~)\_,-C6H3NC) 20: (O) Re-O-Re(O) CI., (CNC~,H ~-( CH.~ ).,-2,6) 2 ] (2). The dinuclear complex 2 was shown by X-ray crystallography to contain an almost linear O=Re-O-Re=O core. Crystals of 2, C~,H.~(,CI4N40~Re,,, are orthorhombic, space group Pccn (No. 56) witha= !!.169(9),b=13.761(4),c--25.831(6) A,Z=4andD,.=l.818gcm --~. © 1998EIsevierScienceS.A.

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Author

F. Ekkehardt Hahn; Lutz Imhof; Thomas Lügger

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

1998

Language

EN

Field

Chemistry (Physical Sciences)