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Can I read Heavy atom solid-state NMR. Mercury-199 spectral simulation and effects of off-magic angle spinning on EtoBox?
Heavy atom solid-state NMR. Mercury-199 spectral simulation and effects of off-magic angle spinning by Christopher J. Groombridge is a Chemistry article available to read on EtoBox.
What is Heavy atom solid-state NMR. Mercury-199 spectral simulation and effects of off-magic angle spinning about?
## Abstract The effects of small deviations from the magic angle on ^199^Hg solid‐state NMR spectra with large chemical shift anisotropy are shown by computation and illustrated with spectra of mercury(II) acetate. These are shown to give the false appearance of multiple species, and place great importance on very precise angle setting (much better than ± 0.1°) for heavy atom solid‐state NMR. Chemical shift tensor principal components have been derived from spinning sideband analysis, and the difficulties of this are discussed; revised values for the anisotropy and asymmetry of mercury(II) acetate are −1732 ppm and 0.08, respectively. ^199^Hg spectra are also given for mercury(II) lactate and citrate.
Who reads Heavy atom solid-state NMR. Mercury-199 spectral simulation and effects of off-magic angle spinning?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Christopher J. Groombridge
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; John Wiley and Sons Ltd; Wiley (ISSN 0749-1581)
- Published
- 1993
- Language
- EN
- Field
- Chemistry (Physical Sciences)