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Mössbauer and electronic spectral studies of iron(III) complexes of oximes by Sulekh Chandra; Sangeetika; Sunil Dutta Sharma is a Chemistry article available to read on EtoBox.

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The hydroxo-bridge complexes of the type [Fe(2)(ligand-H)(4)(OH)(2)] with bidentate nitrogen-oxygen donor ligands, viz. 2-hydroxynaphthaldehydeoxime [hnoH(2)], 2-hydroxyacetphenoneoxime [haoH(2)], salicylaldooxime [SalH(2)], 2-hydroxypropiophenoneoxime [hnoH(2)] have been prepared. All the complexes have been characterized by elemental analysis, magnetic moments, electronic and Mössbauer spectral studies. Mössbauer parameters of the complexes clearly suggest high spin configuration of Fe(III) showing lower magnetic moment to that of the spin only value, i.e. 5.92 BM. It may be due to the antiferromagnetic interaction between Fe(III) centers.

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Author

Sulekh Chandra; Sangeetika; Sunil Dutta Sharma

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Pergamon Press Ltd.; Elsevier BV (ISSN 1386-1425)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)