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Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction 1 Introduction 1 Advance in catalytic materials 6 Noble-metal-based catalysts 6 Facet, structure, and morphology designs 8 Alloying with (non-)metallic-atom effect 9 Sub-nm clusters and single atomic and diatomic pair constructions 10 Noble metal doping 14 Strain engineering 14 Noble metal/non-noble metal compounds hybrids 16 Non-noble metal-based catalysts 16 Fe-based catalysts 16 Co-based catalysts 22 Ni-based catalysts 27 Cu-based catalysts 32 Advances in other active catalysts 39 Conclusion and perspective 40 Bridging fundamental research with NH3 production in practical NOx− resources 42 Cost-effective catalyst in economically viable eNOx−RR systems 42 Key building blocks of the green NH3 society: NOx− electrolyzer technologies 42 Best parameters (rNH3, SNH3, FE...) for evaluating NH3 synthesis performance 43 Initial concentration of NOx− 43 Initial concentration of supporting electrolyte/solutes/ions 44 Valuable anode reactions paired with eNOx−RR 44 Continue to study the same eNOx−RR catalyst 45 In situ reconstruction under eNOx−RR conditions 45 Local microenvironment with less electrostatic repulsio
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