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Can I read Synthesis and characterization of Pd(II) and Pt(II) complexes with triazolopyrimidine derivatives: The crystal structure of [Pd2L2Cl4] where L=5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine on EtoBox?
Synthesis and characterization of Pd(II) and Pt(II) complexes with triazolopyrimidine derivatives: The crystal structure of [Pd2L2Cl4] where L=5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine by Nikos Lekkas; Nick Hadjiliadis; Achilleas Garoufis; Joseph Kobe; Paul V. Bernhardt; Edward R.T. Tiekink is a Chemistry article available to read on EtoBox.
What is Synthesis and characterization of Pd(II) and Pt(II) complexes with triazolopyrimidine derivatives: The crystal structure of [Pd2L2Cl4] where L=5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine about?
The Pd(II) and Pt(II) complexes with triazolopyrimidine C-nucleosides L 1 (5,7-dimethyl-3-( 2 Cl 2 and [Pt 3 (L 1 ) 2 Cl 6 ] were synthesized and characterized by elemental analysis and NMR spectroscopy. The structure of the [Pd 2 (L 3 ) 2 Cl 4 ] AE H 2 O complex was established by Xray crystallography. The two L 3 ligands are found in a head to tail orientation, with a PdÁ Á ÁPd distance of 3.1254(17) A ̊. L 1 coordinates to Pd(II) through N8 and N1 forming polymeric structures. L 2 coordinates to Pd(II) through N8 in acidic solutions (0.1 M HCl) forming complexes of cis-geometry. The Pd(II) coordination to L 2 does not affect the sugar conformation probably due to the high stability of the C-C glycoside bond.
Who reads Synthesis and characterization of Pd(II) and Pt(II) complexes with triazolopyrimidine derivatives: The crystal structure of [Pd2L2Cl4] where L=5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine?
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- Author
- Nikos Lekkas; Nick Hadjiliadis; Achilleas Garoufis; Joseph Kobe; Paul V. Bernhardt; Edward R.T. Tiekink
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
- Published
- 2006
- Language
- EN
- Field
- Chemistry (Physical Sciences)