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This document discusses group contribution methods for predicting vapor-liquid equilibria (VLE) and their development over time. It notes that while over 500,000 binary systems are technically relevant, experimental VLE data is only available for about 2% of these systems. The group contribution method UNIFAC was developed in 1975 to address this issue using groups and interaction parameters fitted to experimental data. Later, modified UNIFAC improved predictions for asymmetric mixtures by incorporating dil

Author

rujunli

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EN