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Densities, isobaric thermal compressibilities and derived thermodynamic properties of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate at t = (298.15 and 308.15) K by Jaime Wisniak; René D. Peralta; Ramiro Infante; Gladis Cortez; R.G. López is a Materials Science article available to read on EtoBox.

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Densities of the binary systems of cyclohexane with allyl methacrylate, butyl methacrylate, methacrylic acid, and vinyl acetate have been measured as a function of the composition, at 298.15 and 308.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes were correlated with the Redlich-Kister equation and with a series of Legendre polynomials. The excess molar volumes are positive for the four binaries studied. Within the short temperature range considered here the coefficient of thermal expansion is positive for all the systems studied; it varies only slightly with the nature of the acrylate except for the system cyclohexane + vinyl acetate.

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Author

Jaime Wisniak; René D. Peralta; Ramiro Infante; Gladis Cortez; R.G. López

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0040-6031)

Published

2005

Language

EN

Field

Materials Science (Physical Sciences)