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Synthesis and reactivity of the first Ag(I) perthiocarboxylates. Crystal structures of tetra(o-tolylperthiocarboxylato)tetra-silver(I), [AgS3C-o-tolyl]4, and of its cocrystallization product with copper(I), [Ag1.76Cu2.24(S3C-o-tolyl)4] by Nazario Marsich; Giorgio Pellizer; Annamaria Camus; Anna Maria Manotti Lanfredi; Franco Ugozzoli is a Chemistry article available to read on EtoBox.

What is Synthesis and reactivity of the first Ag(I) perthiocarboxylates. Crystal structures of tetra(o-tolylperthiocarboxylato)tetra-silver(I), [AgS3C-o-tolyl]4, and of its cocrystallization product with copper(I), [Ag1.76Cu2.24(S3C-o-tolyl)4] about?

## Ag(I)-o-tolylperthiocarboxylate (I) and some Ag(1) arylperthiodithiocarboxylates were prepared by addition of AgNOa to the product isolated from reaction of aldehydes and ammonium polysulfide in basic medium. The X-ray diffraction analysis of I showed that its structure consists of tetranuclear [Ag(S,-CC7H,)]4 complexes and is isomorphous with the corresponding Cu(1) derivative. Mixed crystals of the two pure molecular species, of microscopical structural uniformity, could be obtained. The X-ray diffraction analysis on a suitable crystal of these cocrystallized products yielded a formula [Ag,.,-CU~+,&CC~H,)~] (II); the structure of II is isomorphous with the pure components. Crystals of I and II are both triclinic, space group Pi, with a = Preparation of the Complexes Silver(I) perthiodithiocarboxylates [Ag2(S3CAr)(S2CAr)],

Who reads Synthesis and reactivity of the first Ag(I) perthiocarboxylates. Crystal structures of tetra(o-tolylperthiocarboxylato)tetra-silver(I), [AgS3C-o-tolyl]4, and of its cocrystallization product with copper(I), [Ag1.76Cu2.24(S3C-o-tolyl)4]?

Author

Nazario Marsich; Giorgio Pellizer; Annamaria Camus; Anna Maria Manotti Lanfredi; Franco Ugozzoli

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

1990

Language

EN

Field

Chemistry (Physical Sciences)