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Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids by Eric Palomo; Akhilesh K. Sharma; Zhaofeng Wang; Liyin Jiang; Feliu Maseras; Marcos G. Suero is a Chemistry article available to read on EtoBox.
What is Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids about?
We describe the first catalytic generation of Fischer-type acyloxy Rh(II)-carbenes from carboxylic acids and Rh(II)-carbynoids. This novel class of transient donor/acceptor Rh(II)-carbenes evolved through a cyclopropanation process providing access to densely functionalized cyclopropyl-fused lactones with excellent diastereoselectivity. DFT calculations allowed the analysis of the properties of Rh(II)-carbynoids and acyloxy Rh(II)-carbenes as well as the characterization of the mechanism.
Who reads Generating Fischer-Type Rh-Carbenes with Rh-Carbynoids?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Eric Palomo; Akhilesh K. Sharma; Zhaofeng Wang; Liyin Jiang; Feliu Maseras; Marcos G. Suero
- Publisher
- American Chemical Society (ACS)
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)