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Can I read Di- and Trimanganese N,N′-Dicyclohexylformamidinate Complexes on EtoBox?
Di- and Trimanganese N,N′-Dicyclohexylformamidinate Complexes by Aparna Kasani; Ruppa P. Kamalesh Babu; Khalil Feghali; Sandro Gambarotta; Glenn P. A. Yap; Laurence K. Thompson; Regine Herbst-Irmer is a Chemistry article available to read on EtoBox.
What is Di- and Trimanganese N,N′-Dicyclohexylformamidinate Complexes about?
The reaction of [MnCl 2 (thf) 2 ] with the N,N'-dicyclohexylformamidinate anion gave two remarkably different results depending on the nature of the amidinate alkali metal countercation. The reaction with the lithium salt affords a mixed-valence Mn ± oxo cluster [Mn 3 (CyNCHNCy) 6 OLi] ́2 THF (1), formed by the deoxygenation of THF. In the case of the potassium salt, a dinuclear complex [{(CyNCHNCy)-Mn} 2 (m-CyNCHNCy) 2 ] (2) was formed; it has a highly distorted structure. The complexes 1 and 2 are both extremely sensitive to oxygen. Reaction of 2 with dry O 2 afforded the dinuclear complex [{Mn(CyNCHNCy) 2 } 2 (m-O)] 2 ́2 THF (4).
Who reads Di- and Trimanganese N,N′-Dicyclohexylformamidinate Complexes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Aparna Kasani; Ruppa P. Kamalesh Babu; Khalil Feghali; Sandro Gambarotta; Glenn P. A. Yap; Laurence K. Thompson; Regine Herbst-Irmer
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0947-6539)
- Published
- 1999
- Language
- EN
- Field
- Chemistry (Physical Sciences)