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1. Primary aliphatic amines react with nitrous acid through diazotization to form unstable aliphatic diazonium salts which spontaneously decompose to form mixtures of products. Secondary amines form N-nitrosoamines, while tertiary amines form equilibrium mixtures. 2. Primary arylamines react with nitrous acid to form more stable arenediazonium salts. These salts undergo important replacement reactions where the diazonium group is replaced by groups like halogens, cyanide, or hydroxide in reactions like th

Author

sciencewing rbi

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EN