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Synthesis of 2,6-Diamino-2,6-dideoxy-L-idose by Dr. W. Meyer zu Reckendorf is a Chemistry article available to read on EtoBox.
What is Synthesis of 2,6-Diamino-2,6-dideoxy-L-idose about?
carbene and lithium chloride. Finally, the carbene adds onto the olefinic double bond . H, ,0-R ## F, (1) R = a l k y l ## :c-c< The formation of the cyclopropane derivative takes place in a stereospecific manner as ii cis-addition. I -Vinyl-2-rr-hexoxycyclopropune: A solution iwether of 0.14 mole of methyl-lithium (prepared from methyl iodide -~ a 1.2 N solution) is added dropwise over 2 hours at -5 "C to a stirred solution of 18.5 g (0. I mole) of dichloromethyl n-hexyl ether in 100 ml of butadiene. After hydrolysis with 100 ml of water, the ether layer is separated off, thoroughly washed with water, and dried over calcium chloride. Distillation yields 12.7 g of I-vinyl-2-n-hexoxycyclopropane, b. p. 122 OC/65 mm (isomer ratio 1.3 : 1).
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- Author
- Dr. W. Meyer zu Reckendorf
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley; Research Square (ISSN 0044-8249)
- Published
- 1963
- Language
- EN
- Field
- Chemistry (Physical Sciences)