Can I read Synthesis of Thiazole-containing Benzo-crown Ethers on EtoBox?

Synthesis of Thiazole-containing Benzo-crown Ethers by Hong-Seok Kim; Young Kook Koh; Jun-Hyeak Choi is a Chemistry article available to read on EtoBox.

What is Synthesis of Thiazole-containing Benzo-crown Ethers about?

A series of benzo-crown ethers containing the thiazole subcyclic moity have been synthesized. Reaction of 1,2-bis(thioamidomethyloxy)benzene 2 with ethyl bromopyruvate in ethanol provided 1,2-bis(thiazolyl)benzene \(4(80 \%)\) along with thiazole \(5(14 \%)\). Reduction of 4 with lithium aluminum hydride followed by mesylationbromination gave 7. Similar treatment of 5 with lithium aluminum hydride followed by bromination resulted in 12. Benzo-crown ethers \(8,9,10\), and 13 were prepared from the reactions of 4-bromomethylthiazole derivatives 7 and 12 with catechol and resorcinol derivatives in the presence of potassium hydride.

Who reads Synthesis of Thiazole-containing Benzo-crown Ethers?

Author

Hong-Seok Kim; Young Kook Koh; Jun-Hyeak Choi

Publisher

Journal of Heterocyclic Chemistry; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley; FASEB (ISSN 0022-152X)

Published

1998

Language

EN

Field

Chemistry (Physical Sciences)