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Synthesen und Kristallstrukturen von CsM2P5O16 (M = V, Fe) by Dipl.-Chem. Bernd Klinkert; Prof. Dr. Martin Jansen is a Chemistry article available to read on EtoBox.

What is Synthesen und Kristallstrukturen von CsM2P5O16 (M = V, Fe) about?

Upon heating of mixtures composed cf Cs,CO,, H,PO, and V,O,(Fe,O,) to >GOO"C, melts were formed, from which the title compounds crystallized during slow cooling. They form as well from CsVHP,O,, (CsFeHP,O,,) by condensation, besides (CsPO,),. According to crystal struoture detwminations (Pn; for M = V: a = 763.79(7), b = 941.05(12), c = 1017.29(12) pm, = 111.16(9)'; for M = Fe: a = 752.99(17), b = 937.77(44), c = 1080.90(18) pm, / 3 = 111.02(1)'; Z = 2) the anionic part of both compounds consists of catena-pentaphosphate groups. Systematic variations in the P-0 bond lengths are discussed.

Who reads Synthesen und Kristallstrukturen von CsM2P5O16 (M = V, Fe)?

Author

Dipl.-Chem. Bernd Klinkert; Prof. Dr. Martin Jansen

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

1988

Language

DE

Field

Chemistry (Physical Sciences)