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Chemical Speciation of Environmentally Significant Metals with Inorganic Ligands. Part 3: The Pb2+ + OH–, Cl–, CO3 2–, SO4 2–, and PO4 3– Systems (IUPAC Technical Report) is a Chemistry article available to read on EtoBox.

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Complex formation between Pb II and the common environmental inorganic ligands, Cl -, OH -, CO 3 2-, SO 4 2-, and PO 4 3-, can be significant in natural waters with low concentrations of organic matter. Numerical modeling of the speciation of Pb II among these inorganic ligands requires reliable values for the relevant stability (formation) constants. This paper provides a critical review of such constants and related thermodynamic data. This review is the third in a series relevant to the speciation of heavy metal ions in environmental waters of low to moderate ionic strength. It provides access to the best available equilibrium data for use in chemical speciation modeling of reactions of Pb 2+ with the major inorganic ligands present in environmental systems: Cl -, OH -, CO 3 2-, SO 4 2-, and PO 4 3-. The previous reviews in this series were on the Hg 2+ and Cu 2+ complexation reactions with these ligands.

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Publisher

Walter de Gruyter GmbH

Published

2010

Language

EN

Field

Chemistry (Physical Sciences)