About this Chemistry article
Olefinic Cyclization Promoted by Beckmann Rearrangement of Oxime Sulfonate Synthesis of Dl-muscone by Soichi Sakane; Keiji Maruoka; Hisashi Yamamoto is a Chemistry article available to read on EtoBox.
The acid-catalyzed cyclization of olefinic oxime mesylates has been successfully applied for the synthesis of g-muscone and related macrocycles. We have recently shown that a double bond may become involved in the Lewis acid-catalyzed rearrangement of a suitably constituted olefinic oxime sulfonate and four distinct cyclization modes (Endo(endo, Endo(exo, Exe(B)-endo, Exe(B)-exo) were disclosed.' At the outset of these works, we were interested in the possibility that Endo cyclizations might serve as a powerful tool for ring-transformation reactions.
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- Author
- Soichi Sakane; Keiji Maruoka; Hisashi Yamamoto
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1983
- Language
- EN
- Field
- Chemistry (Physical Sciences)